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Q.

Indicate the complex/complex ion which did not show any geometrical isomerism.

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a

CoCl2en2

b

Co(CN)5(NC)3

c

CoNH33NO23

d

CoNH34Cl2+

answer is B.

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Detailed Solution

(a) CoCl2en2shows cis-trans isomerism.

(b) Co(CN)5(NC)3 is of MA5B type complex, which will not show any isomerism.

(c) CoNH33NO23 shows facial and meridonial isomerism.

(d) CoNH34Cl2+ shows geometrical (cis-trans) isomerism. In cis isomer, two Cl ligands are adjacent to each other. In trans isomer two Cl ligands are opposite to each other.

 Option (b) is correct.

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