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Q.

Industrial Applications and Grades of Anhydrous Sodium Carbonate

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Detailed Solution

Anhydrous sodium carbonate, commonly known as soda ash, is a fundamental industrial chemical with a wide range of applications. Its primary use is as a fluxing agent, an alkali, and a raw material.

Key Industrial Applications:

  • Glass Manufacturing (50-60% of total use): This is its largest application. It acts as a fluxing agent in silica (sand), lowering the melting point of the mixture to a manageable temperature, which significantly reduces energy costs for producing "soda-lime" glass for bottles, windows, and flat glass.
  • Chemical Production: It is a primary base (alkali) used to manufacture a vast array of other chemicals, including sodium bicarbonate (baking soda), sodium silicates, sodium phosphates, and sodium chromates.
  • Detergents and Soaps: It is a key builder in powdered, tablet, and liquid detergents. It acts as a water softener by precipitating magnesium and calcium ions (hardness), which allows the surfactant (cleaning agent) to work more effectively.
  • Pulp and Paper Industry: It is used in the chemical pulping process (sulfite process) to digest wood chips into pulp.
  • Water Treatment: It is used in municipal water treatment to raise the pH (reduce acidity) and to soften water by removing Ca²⁺ and Mg²⁺.
  • Metallurgy: It is used in metallurgy for smelting and refining non-ferrous metals and for desulfurizing iron and steel.
  • Food Industry (Food Grade): It is used as a food additive (E500) as an acidity regulator, an anti-caking agent, and a raising agent.

Grades of Anhydrous Sodium Carbonate

Soda ash is primarily produced in two main grades, which differ in physical properties (like density) but not chemical formula:

  1. Light Soda Ash: This is a fine, white powder. It is produced in the Solvay process before the densification step. Its lower density makes it suitable for applications where it needs to dissolve quickly or be used in powdered formulations, such as in detergents and chemical production.
  2. Dense Soda Ash: This is a granular material, produced by hydrating light soda ash and then dehydrating it in a calciner. This "densification" process creates larger, harder particles. The high density and granular nature are preferred by the glass industry
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