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Q.

Industrial Uses of Calcium Hydroxide (Slaked Lime)

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Detailed Solution

Calcium hydroxide, Ca(OH)2, is a versatile and cost-effective base with wide industrial applications. Below are key sectors and typical roles:

  • Water & Sewage Treatment: Used as a strong, economical alkali for pH adjustment/neutralization of acidic waters (industrial or municipal). Acts as a coagulant aid/flocculant to precipitate dissolved impurities, some heavy metals, and phosphates.
  • Construction (Mortar & Plaster): Essential in traditional lime mortars and plasters. Mixed with sand to form a workable paste that cures by reacting with atmospheric CO2 (carbonation):

 Ca(OH)2(s) + CO2(g) → CaCO3(s) + H2O(l) The formed CaCO3 imparts strength and durability.

  • Agriculture (Soil pH Management): Applied to neutralize acidic soils (“sweetening”), improving nutrient availability and enhancing crop yields. Often used alongside ground limestone (CaCO3) depending on soil requirements.
  • Food Industry: Food-grade Ca(OH)2 is used in nixtamalization of maize (improves nutrition, texture, and milling; e.g., tortillas). Also employed in sugar refining for juice clarification (under regulated conditions and standards).
  • Pulp & Paper (Kraft Process): Vital in causticizing to regenerate NaOH from sodium carbonate in the chemical recovery cycle: Ca(OH)2(aq) + Na2CO3(aq) → 2 NaOH(aq) + CaCO3(s) The precipitated CaCO3 (lime mud) is typically reburned to CaO and recycled.
  • Leather Tanning: Used in liming to swell hides and aid in hair removal during early tanning operations.
  • Flue-Gas Treatment: Employed to scrub acidic gases (e.g., SO2) in emissions control systems, reducing air pollutants.
  • Soil Stabilization (Civil Engineering): Added to clays and subgrades to improve bearing strength, reduce plasticity, and enhance workability for roads and foundations.

Note: Application grades and purity specifications vary by industry (e.g., technical vs. food grade). Follow relevant standards and safety guidelines.

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