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Q.

Initial concentration of the reactant is 1.0M. The concentration becomes 0.9M,0.8M and 0.7M in 2 hours, 4 hours and 6 hours respectively. Then the order of reaction is

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a

2

b

1

c

0

d

3

answer is C.

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Detailed Solution

A zeroth-order reaction is one whose rate is independent of concentration; its differential rate law is rate = k. We refer to these reactions as zeroth order because we could also write their rate in a form such that the exponent of the reactant in the rate law is 0:

rate=−[A]t
=k[reactant]0
=k(1)
=k
so, here in first case rate =(1-0.9)/2 = 0.05

In second case rate=(1-0.7)/6 = 0.05

In third case rate=(1-0.8)/4 = 0.05

Rate constant value for Zero order reaction is constant
So given example is of zero order reaction.


 

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Initial concentration of the reactant is 1.0M. The concentration becomes 0.9M,0.8M and 0.7M in 2 hours, 4 hours and 6 hours respectively. Then the order of reaction is