Q.

In O2,O2  and O22 molecular species, the total number of antibonding electrons respectively are

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a

7, 6, 8 

b

6, 6, 6

c

8, 6, 8

d

1, 0, 2 

answer is A.

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Detailed Solution

Number of electrons in O2- is 17. Molecular orbital electronic configuration of O2- is:

σ1s2σ*1s2σ2s2σ*2s2σ2pz2π2px2=π2py2π*2px2=π*2py1

Number of anti-bonding electrons is 7 and number of bonding electrons is 10.

Number of electrons in O2 is 16. Molecular orbital electronic configuration of O2 is:

σ1s2σ*1s2σ2s2σ*2s2σ2pz2π2py2=π2pz2π*2py1=π*2pz1

Number of bonding electrons in O2 is 10 and number of anti-bonding electrons in O2 is 6.

Number of electrons in O22- is 18. Molecular orbital electronic configuration of O22-is:

σ1s2(σ*1s2)(σ2s2)(σ*2s2)(σ2pz2)(π2px2=π2py2)(π*2px2=π*2py2)

Number of bonding electrons in O22-is 10 and number of anti-bonding electrons in O22-is 8.

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In O2−,O2  and O22− molecular species, the total number of antibonding electrons respectively are