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Q.

In PtC2H42 C2F4 molecule, in which the platinum and all six carbon atoms are almost coplanar, choose the correct statement(s) 

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a

In case of C_2(CN)4 in the complex above, the underlined C-hybridisation is limn3spn

b

CC distance is greater in C2F4 than C2H4

c

If C2H4 is replaced by C2(CN)4 in the complex, then CC distance is greater in C2CN4) than C2F4 . (double bond length)

d

PtC of C2H4 distance is greater than PtC  of C2F4

answer is A, B, C, D.

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Detailed Solution

Here,

C2F4 has greater acceptance of electron into π than C2H4. Hence, CC B.L. of C2H4

Due to synergic bonding MC bond (of C2F4 ) become stronger

C2CN4) also has synergic bonding. Due to back donation from metal to π orbital C=C approaches CC behaviour. sp3.

Thus, all the options are correct

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