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Q.

Inter molecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?

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a

These will form minimum boiling azeotrope

b

ΔmixH=0

c

ΔmixV=0

d

These will not form an ideal solution

answer is C.

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Detailed Solution

Benzene and toluene form ideal solution and for an ideal solution inter molecular forces between two benzene molecules are nearly of same strength as those of between
two toluene molecules. For such solutions,  ΔVmix =0 and ΔHmix =0
Azeotropes are formed only by non-ideal solutions.

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