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Q.

In [Ti(H2O)6]+3 complex the energy absorbed for excitation of 3d1 electron is

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a

Blue-green 

b

Purple 

c

 Red

d

Blue

answer is A.

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Detailed Solution

The colour of [Ti(H2O)6]+3 is violet, however it can turn colourless when heated. The complex's violet color is caused by electron transfer from the t2g to the eg. When an unpaired electron goes from the t2g level to the eg level, it absorbs yellow light and reflects violet light. This is why it seems aggressive in colour.

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In [Ti(H2O)6]+3 complex the energy absorbed for excitation of 3d1 electron is