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Q.

Inversion of sucrose C12H22O11 is first-order reaction and is studied by measuring angle of rotation at different instants of time

C12H22O11+H2OH+C6H12O6+C6H12O6

 Sucrose  Glucose  Fructose ddl

If (r-r0)=a and (r-rt)=(a-x) (where r0,rt and r) are the angle of rotation at the start, at the time t and at the end of the reaction respectively, then there is 50% inversion when :

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a

r0=rtr

b

r0=rt2r

c

r0=rt+r

d

r0=2rtrω

answer is A.

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Detailed Solution

rr0a 

rrt(εx) 

x=a2

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