Q.

Iodide ion is oxidized by acidified dichromate ions as shown in this equation.

Cr2O72(aq)+9I(aq)+14H+(aq)2Cr3+(aq)+3I3(aq)+7H2O(l) 

These data were obtained when the reaction was studied at a constant pH.

Exp.Cr2O72,MI,MRate, M.s-1
10.00400.0100.00050
20.00800.0100.0010
30.01200.0200.0060

What is the order of the reaction with respect to Cr2O72(aq) and  I(aq)?

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a

Second order with respect to both  Cr2O2-7 and I-

b

First order with respect to both  Cr2O2-7 and I-

c

First order with respect to  Cr2O2-7  and second order with respect to I-

d

Second order with respect to  Cr2O2-7  and first order with respect to I-

answer is D.

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Detailed Solution

The order of the reaction with respect to Cr2O72(aq) and  I(aq) is First and second respectively.

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