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Q.

Iodination of benzene is not easily caried out. Hov can one prepare para-iodobcnzoic acid from para-nitrotoluene?

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a

(i) Br2+FeBr3 (ii) Mg in ether, then CO2 {iii) 3H2 and Pt or Ni catalyst (iv) HNO20C(v) KI solution

b

(i) NBS in CCl4 and heat (ii) Nal in aceton (iii) 3H2  and Pt or Ni catalyst (iv) HNO20C (v) H3P02

c

(i) 3H2  and Pt or Ni catalyst (ii) HNO20C (iii) Cu2Br2+HBr (iv) KMn04 and heat (v) KI solution

d

(i) KMn04  and heat (ii) 3H2  and Pt or Ni catalyst (iii) HNO20C (iv) KI solution

answer is C.

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