Iodoform gives a precipitate with AgNO3 on heating but chloroform does not because

Iodoform consists of a weak C−I bond and thus easily hydrolyses to give enough Iˉ ion to react with AgNO3. Chloroform has a stronger bond with the halogen Cl and thus does not easily hydrolyse to provide for Clˉ ions.

Iodoform gives a precipitate with AgNO3 on heating but chloroform does not because

Iodoform consists of a weak C−I bond and thus easily hydrolyses to give enough Iˉ ion to react with AgNO3. Chloroform has a stronger bond with the halogen Cl and thus does not easily hydrolyse to provide for Clˉ ions.

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Iodoform gives a precipitate with AgNO₃ on heating but chloroform does not because

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Chloroform is covalent

Iodoform is ionic

C – I bond in iodoform is strong and C – Cl bond in chloroform is week

C – I bond in iodoform is weak and C – Cl bond in chloroform is strong

answer is C.

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Detailed Solution

Iodoform consists of a weak C−I bond and thus easily hydrolyses to give enough Iˉ ion to react with AgNO₃.
Chloroform has a stronger bond with the halogen Cl and thus does not easily hydrolyse to provide for Clˉ ions.

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