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Q.

Ionic conductivity at infinite dilution of Al3+ and SO42 ions are 189Scm2mol1 and 160Scm2mol1 respectively the equivalent and molar conductivity of Al2(SO4)3 at infinite dilution is x and y. What is x+y

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answer is 1001.

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Detailed Solution

Equalent conductance λ0=1n+.λ+0+1n.λ0

Where n+ and n- are charge on each ion

λ0Al2(so4)3=1n+λ0Al3++1nλ0so42                  =13λ0Al3++12λ0so42                 =13×189+12×160               =143S   cm2eq1=x

Molar conductance at infinite dilution 0=γ+.λ+0+γ.λ0

Where γ+ and γ- are the number of +ve and -ve ions

0Al2(so4)3=γ+.λ0Al3++γ.λ0so42                  =2×189+3×160                 =858S   cm2mol1=y   x+y=143+858=1001

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