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Q.

Ionisation energy of He+ is I9.6x 10-18 J atom-1 . The energy of the first stationary state 

(n = 1) of Li2+ is

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a

8.82×1017J atom 1

b

4.41×1016J atom 1

c

4.41×1017J atom 1

d

2.2×1015J atom 1

answer is C.

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Detailed Solution

En=13.6Z2n2eV
EZ2
 Ionization energy of He+=E1=19.6×1018J atom 1 (given) 
E1 for Li+2=?
EHe+ELi+2=(2)2(3)2=49
ELi+2=9419.6×1018=44.1×1018
=4.41×1017J atom 1

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