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Q.

Ionization energy of atoms A and B are 360 and 260  kcal mol -1 respectively. The electron affinities of these atoms are 70  kcal mol -1 and 90  kcal mol -1 respectively, then :

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a

Electron cloud is more attracted by A

b

Electron cloud is more attracted by B

c

Electronegativity of A is more than B

d

Electronegativity of A is less than B

answer is A, C.

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Detailed Solution

Given,

IE(A) = 360 kcal mol -1

IE(B) = 260 kcal mol -1

EA(A) = 70 kcal mol -1

EA(B) = 90 kcal mol -1

Electron cloud is more attracted to those atoms having more ionization energy. Hence, Electron cloud is more attracted by atom A.

The relationship between the electron affinity and ionization energy is

 A (IE)=−(EA). So that the atoms having the more ionization energy has high value of electron affinity.

=ENA350+70 =ENB250+90=ENA>ENB

Hence, option A and C are correct.

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