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is least reactive towards nitration when 'A' is

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$N O_{2}$

$C H_{3}$

$N H_{2}$

$C l$

answer is B.

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Detailed Solution

Nitro group reduces the electron density in the benzene ring due to its strong–I effect. Nitrobenzene is a resonance hybrid of the following structures

A Simple Note on Resonance Structures of Nitrobenzene

In this case, the overall electron density on benzene ring decreases making further
substitution difficult.

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