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Q.

i) S+O2SO2 ΔH=-298.2 kJ

ii) SO2+1/2O2SO3 ΔH=-98.7 kJ

iii) SO3+H2OH2SO4 ΔH=-130.2 kJ

iii) H2+1/2O2H2O ΔH=-287.3 kJ

The enthalpy of formation of H2SO4 at 298 K is:

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a

-814.4 kJ

b

-650.3 kJ

c

320.5 kJ

d

-433.5 kJ

 

answer is A.

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Detailed Solution

Enthalpy of formation of H2SO4 is represented by the reaction as follows:

H2+S+2O2H2SO4

From the given reactions,

S+O2SO2ΔH1=-298.2 kJSO2+1/2O2SO3ΔH2=-98.7 kJSO3+H2OH2SO4ΔH3=-130.2 kJH2+1/2O2H2OΔH4=-287.3 kJ

On (i) +( ii )+( iii )+( iv) we get,

H2+S+2O2H2SO4 ΔH=ΔH1+ΔH2+ΔH3+ΔH4 ΔH=-298.2-98.7-130.2-287.3 ΔH=-814.4

Hence, option (A) is correct.

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