Q.

Isobutane reacts with chlorine in sunlight to produce 1-Chloro-2-methyl propane 68% and 2-Chloro-2-methyl propane 32% of the total yield. Under similar conditions propane reacts with chlorine in sunlight to produce 1-Chloropropane 45% & 2-Chloropropane 55% of total yield. 
The percentage yield of the major product obtained by monochlorination of 1,3,5 -trimethyl cyclohexane is  x×10%. The value of  x will be           

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answer is 5.

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Detailed Solution

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From given datas we will get the reactivity order of hydrogen’s which is 1:3.66:4.23

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P1:P2:P3=n1r1:n2r2;n3r3 =1×9:6×3.66:3×4.23 =9:21.96:12.70 % of P2 (major)  =50 X=5

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Isobutane reacts with chlorine in sunlight to produce 1-Chloro-2-methyl propane 68% and 2-Chloro-2-methyl propane 32% of the total yield. Under similar conditions propane reacts with chlorine in sunlight to produce 1-Chloropropane 45% & 2-Chloropropane 55% of total yield. The percentage yield of the major product obtained by monochlorination of 1,3,5 -trimethyl cyclohexane is  x×10%. The value of  x will be