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Q.

 Isomeric amines with molecular formula C8H11N give the following tests   Isomer (P) Can be prepared by Gabriel phthalimide synthesis   Isomer (Q) Reacts with Hinsberg's reagent to give solid insoluble in NaOH  Isomer (R) Reacts with HONO followed by β - naphthol in NaOH to give red dye.   Isomer (P),(Q) and (R) respectively are 

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a

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b

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c

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d

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answer is A.

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Detailed Solution

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Gabriel synthesis is used to prepared aliphatic primary amines 2° amine with hinsberg reagent gives a ppt which is insoluble in NaOH Aromatic amines reacts HONO

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