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Q.

 Isopropylalcohol H+/K2Cr2O7 final product 

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a

Propanol

b

Ethanoic acid

c

Ethanal 

d

Propene

answer is D.

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Detailed Solution

Isopropyl alcohol (CH3CH(OH)CH3) undergoes oxidation when treated with an oxidizing agent like K2Cr2O7 (Potassium Dichromate) in acidic conditions. Potassium dichromate is a powerful oxidizing agent that can oxidize alcohols in a two-step process. Let’s break down the oxidation process in detail:

Step 1: Oxidation to Aldehyde

In the presence of K2Cr2O7 and an acidic medium, isopropyl alcohol undergoes the first stage of oxidation. The hydroxyl group (-OH) in isopropyl alcohol is oxidized to form an aldehyde. The reaction proceeds as follows:

CH3CH(OH)CH3  →  CH3COH (Acetaldehyde)    

Step 2: Further Oxidation to Carboxylic Acid

Upon continued oxidation, the aldehyde (Acetaldehyde) undergoes further oxidation to form a carboxylic acid. The second stage of oxidation converts the aldehyde into acetic acid (ethanoic acid). This transformation is facilitated by the presence of K2Cr2O7 in acidic conditions:

CH3COH (Acetaldehyde)  →  CH3COOH (Acetic acid)    

Overall Reaction

The complete reaction, where isopropyl alcohol is oxidized to acetic acid (ethanoic acid) by K2Cr2O7, is shown below:

CH3CH(OH)CH3 + H+ / K2Cr2O7  →  CH3COOH + CH4    

Conclusion

Hence, when isopropyl alcohol is treated with K2Cr2O7 in the presence of an acidic medium, it undergoes oxidation to form acetic acid (ethanoic acid). Therefore, the correct final product is ethanoic acid.

The correct answer is option (D) Ethanoic Acid.

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