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Isostructural species are those which have the same shape and hybridisation. Among the given species identify the isostructural pairs.

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$[{BF}_{4}^{-} and {NH}_{4}^{+}]$

$[{NF}_{3} and {BF}_{3}]$

$[{NH}_{3} and {NO}_{3}^{-}]$

$[{BCl}_{3} and {BrCl}_{3}]$

answer is B.

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Detailed Solution

${BF}_{4}^{-}$ and ${NH}^{+}_{4}$ are isostructural as both has the same structure (tetrahedral) and both has the same hybridization which is ${sp}^{3}$ .

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