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Q.

Isostructural species are those which have the same shape . Among the given species identify the isostructural pairs.

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a

[NF₃ and BF₃]

b

$[H_{3} O^{+} and {CH}_{3}^{-}]$

c

$[{BCl}_{3} and {BrCl}_{3}]$

d

$[{NH}_{3} and {NO}_{3}^{-}]$

answer is B.

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Detailed Solution

detailed_solution_thumbnail

NF₃ is pyramidal whereas BF₃ is planar triangular.
$open square brackets straight H subscript 3 straight O to the power of plus text and end text CH subscript 3 superscript minus close square brackets$ ions both are pyramidal
BCl₃ is triangular planar whereas BrCl₃ is pyramidal.
NH₃ is pyramidal whereas $N O_{3}^{-}$ is triangular planar.

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