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Q.

It has been found that for a chemical reaction with rise in temperature by 9K the rate constant gets doubled. Assuming a reaction to be occurring at 300K, the value of activation energy is found to be _____ kJmol-1. [nearest integer]
(Given ln10=2.3,R=8.3JK-1 mol-1,log2=0.30 )

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answer is 59.

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Detailed Solution

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log10K2 K1=Ea2.303R1300-1309
0.3=Ea2.303×8.39300×309


Ea=0.3×2.303×8.3×300×3099       =59065.04 J Ea=59.06 kJ

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