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Q.

IUPAC name of  K4FeCN6 is

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a

Tetrapotassium hexacyanoferrate (II)

b

Potassium hexacyanatoferrate(II)

c

Potassium hexacyanoferrate(II)

d

Potassium hexacyano Iron(II)

answer is C.

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Detailed Solution

A) Name cation first .
B) While naming counter ions prefixes like  di, tri, tetra should not be used.
C) While naming complex, ligand is named first with proper prefix.
D) CN is cyano (or) cyanido.
E) For anionic complex, the suffix –ate must be used after the name of metal ion
D) Oxidation number of central metal ion must be written as roman number in parenthesis
  Potassium  Hexacyanoferrate(II)
(or)
Potassium hexacyanidoferrate(II)

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IUPAC name of  K4FeCN6 is