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Q.

IUPAC name of the complex, K3FeCN6 is

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a

Potassium hexacyanido ferrate(II) 

b

Potassium hexacyanido ferrate(III) 

c

Potassium hexacyanato ferrate(II) 

d

tripotassium hexacyanido ferrate(III) 

answer is A.

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Detailed Solution

CN-…cyanido or cyano(preferably cyanido)…uninegative ligand ;

Oxidation state of iron is “+3” ;

Counter ion is potassium ion and while naming the counter ion  prefixes like di, tri…should not be used;

Complex ion is an anion, it should be written after name of cation;

While naming the complex, ligands are named first (in alphabetical order with proper prefixes) followed by metal ion with its oxidation state as roman number in parenthesis;

While naming the metal ion of an anionic complex the suffix “ate” is used;

 

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