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IUPAC name of the compound with the molecular formula $C_{4} H_{9} Br$ and least possible boiling point is

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1–Bromobutane

2–Bromobutane

2–Bromo–2–methylpropane

1–Bromo–2–methylpropane

answer is A.

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Detailed Solution

Tert-Butyl bromide (also known as 2-bromo-2-methylpropane) is a chemical having the formula ${({CH}_{3})}_{3} C - Br$ . As the number of branches increases Boiling point Decreases.

Hence, the correct answer is option (A) 2–Bromo–2–methylpropane.

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