K, A and E_a of a process at 25⁰c respectively are $5\times {10}^{-4}{\mathrm{s}}^{-1}$,$6\times {10}^{14}{\mathrm{s}}^{-1}$and 108 kj/mol. Then the value of rate constant as time $\to \infty$, will be (in s^-1)