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Q.

K3[Al(C2O4)3] is called

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a

Potassium trioxalatoaluminate (VI)

b

Potassium aluminium (III) oxalate

c

Potassium trioxalatoaluminate (III)

d

Potassium aluminooxalate

answer is B.

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Detailed Solution

Potassium trioxalatoaluminate (III)

Explanation:

  • Identification of Ions:
    • Cation: Three potassium ions (K⁺).
    • Anion: The complex ion [Al(C₂O₄)₃]³⁻.
  • Naming the Complex Ion:
    • Ligand: The oxalate ion (C₂O₄²⁻) is a bidentate ligand, named as 'oxalato'.
    • Quantity of Ligands: Three oxalate ligands are present, denoted by the prefix 'tri'.
    • Central Metal Ion: Aluminum (Al) in an anionic complex is named 'aluminate'.
    • Oxidation State: The oxidation state of aluminum is +3, represented as '(III)'.
  • Constructing the Name:
    • Cation: 'Potassium'
    • Anion: 'Trioxalatoaluminate (III)'
    • Full Name: Potassium trioxalatoaluminate (III).

Oxidation State Calculation:

  • Oxalate Ligand Charge: Each oxalate ion carries a charge of -2.
  • Total Charge from Ligands: 3 × (-2) = -6.
  • Overall Complex Charge: -3.
  • Aluminum Oxidation State (x):
    • x + (-6) = -3
    • x - 6 = -3
    • x = +3

Therefore, the oxidation state of aluminum in this compound is +3.

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