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Q.

Ka Values of 5 weak acids are given as HA=108 .HB=106  .  HC=2×108 HD=1010HE=107    Select the correct statement /s as per information  (log2=0.3010,Kw=1014)

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a

Among NaA, NaB, NaC, NaD & NaE the NaD is most extensively hydrolyzed

b

Among NaA, NaB, NaC, NaD & NaE the NaB is most extensively hydrolyzed 

c

pH of 0.1M aq solution of NaB is approximately 9.5 

d

0.1M solution of HE & 0.01M solution of HB are isohydric to each other approximately

answer is A, D, C.

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Detailed Solution

 Kn=KwKa
Higher the value of Kn , more extensively hydrolyzed
 PH=7+12Pka+12logc
Isohydric solution  PHEH=PHBH
 

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