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Q.

Ka1,Ka2 and Ka3, are the respective ionisation constants for the following reactions.
H2SH++HS HSH++S2 H2S2H++S2
The correct relationship between Ka1,Ka2 and Ka3 is

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a

Ka3=Ka1/Ka2

b

Ka3=Ka1+Ka2

c

Ka3=Ka1×Ka2

d

Ka3=Ka1Ka2

answer is A.

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Detailed Solution

 For the reaction, H2SH++HS Ka1H+HSH2S  For the reaction,  HSH++S2;Ka2=H+S2HS 
When the above two reactions are added, their equilibrium constants are multiplied, thus

Ka3=H+2S2H2S=Ka1×Ka2 Hence Ka3=Ka1×Ka2

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