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Q.

kaofHCNandCH3COOH are respectively 4.5×1010 and 1.5×105 at 298k.Thus, equilibrium constant for CN+CH3COOH CH3COO+HCN would be

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a

3.3×104

b

3.1×105

c

3.2×105

d

3.3×104

answer is D.

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Detailed Solution

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HCN H++CN  ka=4.5×1010CH3COOH H++CH3COO,  ka1=1.5×105CN+H+ HCN   ka2=1kaCH3COOH+CN HCN+CH3COO,  keq=ka'ka"=1.5×105×14.5×1010=3.33×10+4

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ka of HCN and CH3COOH are respectively 4.5×10−10 and 1.5×10−5 at 298k.Thus, equilibrium constant for CN−+CH3COOH⇌ CH3COO−+HCN would be