Q.

KBr is doped with 105 mole percent of SrBr2. The number of cationic vacancies in 1 g of KBr crystal is___×1014

(Atomic Mass:  K=39.1u, Br=79.9uNA=6.023×1023)

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answer is 5.

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Detailed Solution

Atomic mass of potassium is 39.1 u and atomic mass of bromine is 79 u. One cationic vacancy approved by one Sr2+ ion. Number of Sr2+ ions is equal to the number of cationic vacancies.

Since the mole percentage of SrBr2 dopped is 10-5 to that of total moles of KBr.

Hence, the number of cationic vacancies:
Number of cationic vacancies=105100×119×6.022×1023=5x×1014

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