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Q.

KC for N2 + O2  2NO at certain temperature is 1.6 × 10-3, then KP for NO  1/2N2 + 1/2O2 at same temperature will be.

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a

25 atm

b

5 atm

c

25

d

1.6×10-3 atm-1

answer is A.

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Detailed Solution

Given: it is given that Kc=1.6×10-3 atm for reaction 1st: N2+O22NO

We have to find Kp for reaction 2nd: NO1/2N2+1/2O2

Formula Used: Kp=Kc(RT)Δn;Δn=np-nr 

Explanation: For reaction 1st, np=2 and nr=1+1=2 ; therefore, Δn=2-2=0 and Kp=Kc=1.6×10-3

In reaction 2nd, NO gives 1/2N2+1/2O2 i.e., ½ of the inverse of reaction 1st,

Therefore, Kp'=1/(Kp)1/2=1/(1.6×10-3)1/2=25  

Hence, the correct option is A i.e., 25.

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