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Q.

KH of N2 is 1×105 atm. The moles of N2 dissolved in 10 mol water is (given pressure of air is 5 atm and mole fraction of N2 in air is 0.8)

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a

4×10-5

b

5×10-2

c

5×10-4

d

4×10-4

answer is A.

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Detailed Solution

KH of N2 =1×105 atm

Given pressure of air = 5 atm 

mole fraction of N2 in air = 0.8

Pressure of N2 = Pressure of air × mole fraction of N2 

=5×0.8=4 atm

By Henry's law

 Pressure of N2 = KH × mole fraction of N2 

mole fraction = Pressure of N2KH=41×105=4×10-5

For 1 mole of water of 4×10-5 N2 moles are dissolved

For 10 mole of water of 4×10-5×10 N2 moles are dissolved =4×10-4

Hence, the required answer is A) 4×10-4

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