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Q.

K.I. (aq.) + 'A' (reagent)

 [Brown solution of 'B']

       [White ppt. of 'C'] 

Compound 'A" and 'C' may be:

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a

 Pb(OAc)2 and PbI2

b

FeSO4 and FeS4O6

c

HgCl2 and Hg2I2

d

CuSO4 and Cu2I2

answer is B.

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Detailed Solution

When copper sulphate  CuSO4  is treated with potassium iodide (KI), it precipitates cuprous iodide  (Cu2I2)  liberates iodine gas I2 and produces potassium sulphate K2SO4

 (K.I. (aq.) +CuSO4(reagent)Brown solution of 'B'+Na2S2O3Cu2I2

 

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