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Q.

Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from 0.55 g of the compound neutralised 12.5 mL of 1 M H2SO4 solution. The percentage of nitrogen in the compound is__________.(Nearest integer)

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answer is 64.

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Detailed Solution

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Meq of H2SO4 used by NH3 = 12.5 × 1 × 2 = 25
% of N in the compound = 25×103×14×1000.55=63.6
or
Meq. of H2SO4 = Meq. of NH3
12. 5 × 1 × 2 = 25 meq. of NH3
= 25 millimoles of NH3
So Millimoles of 'N' = 25
Moles of 'N' = 25 × 10–3
wt. of N = 14 × 25×10–3
%N=14×25×1030.55×100=63.6664%

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