Q.

KMnO4​ can be prepared from K2​MnO4 as per the reaction:

3MnO42-+2H2O2MnO4-+MnO2+4OH
The reaction can go to completion by removing OH ions by adding:

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a

SO2

b

CO2

c

HCl

d

KOH

answer is A.

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Detailed Solution

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3MnO42+2H2O2MnO4+MnO2+4OH
Removal of OH is favourable for the formation of KMnO4 , i.e., forward reaction. To remove OH ion, a weak acid is required because a strong acid reverses the reaction. So here, among all, CO2 is the weak acid that combines with OH ion to give carbonate, which is easily removed.
(2)  (O) +SO2+H2OH2SO4
H2SO4  is a strong acid, which will reverse equilibrium reaction.
(3) HCl is a strong acid, which favors equilibrium in backward reaction.

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