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Q.

Knowing that the chemistry of lanthanoids(Ln) is dominated by its +3 oxidation state, which of the following statements is incorrect?

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a

Because of the large size of the Ln(III) ions the bonding in its compounds is predominantly ionic in character

b

Ln(III) compounds are generally colourless

c

The ionic sizes of Ln(III) decrease in general with increasing atomic number

d

Ln(III) hydroxides are mainly basic in character

answer is A.

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Detailed Solution

The compounds of Ln(III) are generally coloured due to the presence of unpaired electron(s) in 4f orbitals. The promotion of electron within the f orbitals is responsible for the colour of the compounds.

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