Q.

Ksp of PbBr2 is 8 x 10-5. If the salt is 80% dissociated in solution. The solubility of salt in gL-1 is P+3.48 then the value of P is.

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answer is 9.

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Detailed Solution

Let the solubility of PbBr2 be S mol L-1
pbBr2(s)pbBr2(aq)pbaq+2+2Braq
Ionisation of pbBr2 = 80%  s×80100;2s×80100
Ksp=pb+2Br28×105=S×801002S×801002
From this S = 0.034 mol L-1 
MW of pbBr2 = 367 
Solubility S = 0.034 mol L-1 =0.034 x 367 gL-1 = 12.48 
12.48 = P + 3.48 
P =12.48 – 3.48 = 9

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