${\mathrm{K}}_{\mathrm{sp}}\left({\mathrm{BaSO}}_4\right)$ is  $1.1\times {10}^{-10}$. In which case is ${\mathrm{BaSO}}_4$ precipitated?

100 mL of $4\times {10}^{-4}\text{M}$  of

${\mathrm{BaCl}}_2+100\mathrm{mL}\text{\hspace{0.17em}of\hspace{0.17em} 6.0}\times {\text{10}}^{-8}\mathrm{M}{\text{\hspace{0.17em}of Na}}_2{\mathrm{SO}}_4$ 

100 mL of $4\times {10}^{-3}\mathrm{M}$ of

${\mathrm{BaCl}}_2+300\mathrm{mL}\text{\hspace{0.17em}of\hspace{0.17em} 6.0}\times {\text{10}}^{-4}\mathrm{M}{\text{\hspace{0.17em}of Na}}_2{\mathrm{SO}}_4$

100 mL of  $4\times {10}^{-4}$M of

${\mathrm{BaCl}}_2+300\mathrm{mL}\text{\hspace{0.17em}of\hspace{0.17em} 6}\times {\text{10}}^{-8}\mathrm{M}{\text{\hspace{0.17em}of Na}}_2{\mathrm{SO}}_4$

In all cases