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Q.

 Ksp of AgCl is 1.96×1010. 100 mL of saturated AgCl solution is titrated with 1×105M NH4SCN. Volume of 1×105M NH4SCN required to precipitate all Ag+ from saturated AgCl solution as AgSCN is:

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a

140 mL

b

260 mL

c

70 mL

d

200 mL

answer is A.

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Detailed Solution

Ag+=1.96×105

nAg+(100 mL)=1.96×106

Ag++SCN    AgSCN6    1.96×106    =105×V        V=0.14L

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