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Q.

Ksp of AgCl=1.0×1010. Select the incorrect statement(s). 

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a

pAg+pCl=10

b

pAg+pCl<10 in presence of Ag+

c

pAg=pCl=5 in saturated AgCl solution 

d

pCl=8 in 0.01M Ag+

answer is C.

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Detailed Solution

Ag+Cl=Ksp=1×1010 
 

Question Image

 pAq+pCl=10
Hence, (a) is true.
 In 0.01 M Ag+, Cl=1×10100.01=1×108
 pCl=8
Hence, (b) is true.
 In all cases pAq+pCl=10 for AgCl at a given temperature. 
Thus, (c) is incorrect.
Since, Ag+=Cl
 Ag+=Cl=Ksp=105M logAg+=logCl=5 logAg+=logCl=5 pAg=pCl=5 
Hence, (d) is also true.

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