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Q.

Ksp of AgCl, Ag2CrO4 and  AgBr are 1010, 1013 and 1012 respectively. If to a solution of 0.1 M each of Cl, CrO42 and Br ions, AgNO3 is added slowly, which will precipitate first :

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a

AgCl

b

AgBr

c

Ag2CrO4

d

All simultaneously

answer is C.

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Detailed Solution

Ag+ required in each case :

(a) AgCl1010101=109M

(b) Ag2CrO41013101=106M

(c) AgBr1012101=1011M

Correct option is C.

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