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Q.

L-isomer of a compound 'A'  C4H8O4 gives a positive test with AgNH32+ Treatment of  ‘A’ with acetic anhydride yields triacetate derivative. Compound ‘A’ produces an optically active compounds (B) and an optically inactive compound (C) on treatment with bromine water and HNO3 respectively. Compound (A) is:
 

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a

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b

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c

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d

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answer is A.

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Detailed Solution

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C6H8O4DU=1      (A)
A[Ag(NH3)2]++vetest    (can  be=CHO) ABr2+H2OOptically active  AConc.HNO3Optically inactive  A(CH2CO)2OTriacetate derivative
Three  -OH groups
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L-isomer of a compound 'A'  C4H8O4 gives a positive test with AgNH32+ Treatment of  ‘A’ with acetic anhydride yields triacetate derivative. Compound ‘A’ produces an optically active compounds (B) and an optically inactive compound (C) on treatment with bromine water and HNO3 respectively. Compound (A) is: