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Q.

Lanthanide contraction is caused due to :

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a

the imperfect shielding on outer electrons by 4f electrons from the nuclear charge

b

the same effective nuclear charge from Ce to Lu

c

the appreciable shielding on outer electrons by 4f electrons from the nuclear charge

d

the appreciable shielding on outer electrons by 5d electrons from the nuclear charge

answer is B.

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Detailed Solution

Lanthanide contraction is caused due to the imperfect shielding of outer electrons by 4f electrons from the nuclear charge.

A lower atomic radius derives from the lanthanoid contraction effect, which is caused by 4f electrons' insufficient ability to buffer nuclear charge (the force that attracts electrons toward the nucleus).

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