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Law of mass action is not applicable to following physical equilibrium reaction $H_{2} O_{(l)} ⇌ H_{2} O_{(g)}$ . The reason for the statement is ____?

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The process is not spontaneous at all temperatures

The concentration or vapor pressure of pure substance remain constant at given temperature

The process is endothermic in nature.

The process is spontaneous at all temperatures.

answer is B.

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Detailed Solution

For pure components their concentration and vapor pressure remain constant at given temperature so, law of mass action is not applicable to physical equilibria.

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