Let a circle C in complex plane pass through the points ${\mathrm{z}}_1=3+4\mathrm{i}, {\mathrm{z}}_2=4+3\mathrm{i}$ and ${\mathrm{z}}_3=5\mathrm{i}$. If $\mathrm{z}\left(\ne {\mathrm{z}}_1\right)$ is a point on C such that the line through z and ${\mathrm{z}}_1$ is perpendicular to the line through ${\mathrm{z}}_2$ and ${\mathrm{z}}_3$, then $\arg \left(\mathrm{z}\right)$ is equal to :