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Q.

Let a fully charged lead-storage battery contains 1.5L of 5M H2SO4. What will be the concentration of H2SO4 in the battery after 2.5A current is drawn from the battery for 6 hour?

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a

0.373 M

b

4.626 M

c

9.627 M

d

0.1866 M

answer is B.

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Detailed Solution

Number of moles of H2SO4 before electrolysis=MV1000=5×1.5×10001000=7.5
Amount of H2SO4 used,

=1tE96500=2.5×6×3600×6896500=54.839g=54.83998mol=0.56mol
Remaining mol of H2SO4= 7.5 – 0.56 = 6.94
Remaining molarity nV×1000=6.941.5×1000×1000=4.626

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