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Q.

Let  CNaCl and CBaSO4 be the conductance (in S) measured for saturated aqueous solutions of NaCl and BaSO4 , respectively, at a temperature T.

          Which of the following is false ?

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a

Ionic mobilities of ions from both salts increase with T.

b

CNaCl>>CBaSO4 at a given T

c

CNaClT2>CNaClT1 for T2>T1

d

CBaSO4 T2>CBaSO4 T1 for T2>T1

answer is B.

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Detailed Solution

Here, NaCl is strong electrolyte so it ions completely at room temperature. So its ionisation no changes (V-U less extent charge) with increase of temperature. But BaSO4 is weak electrolyte and hence its conductance increases with temperature.

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