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Q.

Limiting value of equivalent conductance of BaSO4, BaCl2 and H2SO4 are X, Y and Z respectively.

Equivalent conductance of HCI at infinite dilution is

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a

 Y+Z-X

b

12(Z+X-Y)

c

12(Y+Z-X)

d

12(X+Y-Z)

answer is D.

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Detailed Solution

The reaction is : 

H2SO4​ + BaCl2​ ⟶ 2HCl + BaSO4 

So, The equivalent conductance of HCl at infinite dilution is 

  = [ ( λeq° )BaCl2+ ( λeq° )H2SO4 - ( λeq° )BaSO4 ] 

  = 12( Y + Z - X )

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